Spectroscopy and Atmospheric Chemical Kinetics
Innumerable varieties of the chemical compounds are released into the Earth's atmosphere via natural, anthropogenic and biogenic emissions. These compounds show adverse effects such as influence on the climate, eco system and human health directly or indirectly. One such adverse effects is the well known Antarctic ozone hole formation because of the chlorofluorocarbons (CFCs). This has lifted the eyebrows of the scientific community and the search for alternatives was initiated after the CFC were banned at the Montreal protocol. Therefore, it is very essential to understand the fate of each compound in the Earth's atmosphere before their usage in any form. In our research laboratory, efforts for such an understanding on many compounds that are being released into the Earth's atmosphere are initiated. The compounds of our interest include starting from the alternatives compounds to CFCs till the recent bio-fuels and their additives. Although many physical and chemical properties are needed to be explored, we measure the kinetic parameters of the reactions of these compounds with the oxidizing agents as a first step.
All the compounds those are released into the Earth's atmosphere, undergo either physical or chemical processes. The physical processes include absorption of light and thus initiated photochemical processes. The chemical processes include the reaction of these compounds with abundant oxidising species to form transient species and thereby contribute significantly to the chemical composition of the Earth's atmosphere. To understand the complete fate of a molecule that is released into the Earth's atmosphere, the research work carried out in our laboratory is broadly categorized into two domains accordingly.
SpectroscopyThe absorption of light at a suitable wavelength by a molecule leads to the photodissociation into several radicals or transient species. Therefore, the quantum yields, absorption cross-section of the formed radicals and their loss processes via chemical reactions are needed to be studied to have a complete picture of any molecules of importance in the atmosphere. To achieve this goal, a state of the art instrument called "Cavity Ring-Down Spectrometer (CRDS)" has been built in our laboratory. In simple words, a photon is trapped in a highly reflective optical cavity and it is allowed to travel between them to enhance its optical path length.
About 20-50 km optical path length is just very trial to be achieved using this technique. This very high optical path length makes the technique super sensitive and will enable to detect trace gasses even when the concentrations are as low as ppb. Using the CRDS, one can measure- (i) The absorption cross sections of any transient species or radical; (ii) Quantum yield of formation of such a radical & also the (iii) Kinetics of radical-radical,radical-molecular reactions. All these studies are being presently carried out in our laboratory.
The inbuilt pulsed laser photolysis Cavity Ring Down Spectrometer (PLP-CRDS) in our old lab. The photolsis and probe beam arms of the PLP-CRDS setup are perpendicular to each other.
The experimentally measured absorption spectrum of o-xylyl radical at (298 ± 2) K in the wavelength range of 460.1–475.1 nm with 0.2 nm resolution. The absorption maximum was observed at 468.3 nm and the vertical bars represent errors in 2σ. [Bej et al., Chem. Phys. Lett. 2021, 765, 138314]
Atmospheric Chemical KineticsThe lifetime of any compound released into the Earth's atmosphere depends on the rates of their reactions with the oxidizing species such as hydroxyl radicals (OH), Cl atoms, NO3 radicals etc. The lifetimes of the compounds can be estimated using the measured kinetic parameters in the temperatures relevant to the atmospheric conditions. We adopt two methods namely relative rate (RR) method and Pulsed Laser Photolysis - Laser Induced Fluorescence (PLP-LIF) method, for the purpose of these measurements. In the RR method, the rate kinetic parameters are measured relative to a known reaction. The PLP-LIF method is an absolute method, wherein the concentration of one of the species is measured using an induced fluorescence. The kinetic parameters are obtained using the measured temporal profile of that species.
The designed PLP-LIF cell to carry out the absolute rate measurements
An in-built crossed pulsed laser photolysis Cavity Ring-Down Spectroscopy (CRDS) reaction cell in our laboratory
Collinear Photolysis Cavity Ring-Down Spectroscopy (CoP-CRDS)
New in-built colinear PLP-CRDS setup which will enhance the detection sensitivity due to its increased length of effective absorption. The angle between the photolysis and probe beam arms of the reaction cell has been kept ~45 degrees.
Schematic representation of the pulsed laser photolysis-laser induced fluorescence (PLP-LIF) setup in our laboratory of atmospheric processes at the department of Chemistry of IIT Madras. DAQ: Data Acquisition Card; MFC: Mass Flow Controllers.
Left to Right (over optical table): Nd:YAG pumped dye laser; colinear PLP-CRDS setup; 248 nm KrF excimer laser (ns, pulsed). Right down corner: PLP-LIF setup. Farthest corner top right: GC-MS, GC-IR instruments. Top (hanging over optical table): calibrated mass flow controllers. The optical table also accommodates baratron pressure gauges, gas mixing chamber, photo-multiplier tube (PMT), box-car integrator, optical mounts for alignment purpose, delay generators etc. The complete gas handling system can also be seen in this picture.
Cross Photolysis Cavity Ring-Down Spectroscopy (CP-CRDS)
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[su_tab title="COMBUSTION CHEMISTRY"]
Combustion Chemistry
Fossil fuels are the major source of energy in the present era. The usage of the fossil fuels takes the major stake as the source for the energy till 2040. The usage of these fuels led to the generation of greenhouse gasses and they are released into the Earth's atmosphere. This is a serious threat in terms of global warming. Therefore, the usage of biofuels as renewable sources seems to be one alternative source for the energy in addition to solar energy and nuclear energy. Although biofuels are acceptable, the emission of greenhouse gasses in the process of combustion should be seriously considered. The reaction mechanisms for the combustion of bigger molecules are much more complicated and lead to various products which may be harmful to atmosphere. Combustion of a fuel can be divided into two categories, complete and incomplete combustion. In complete combustion, fuels burn in oxygen and produce CO2 and H2O as primary products. Incomplete combustion will occur when there is not enough oxygen to allow the fuel to react completely to produce CO2 and H2O. For most of the fuels, such as diesel oil, coal and wood, pyrolysis occurs before combustion. In incomplete combustion, products of pyrolysis remain unburnt and contaminate the smoke with noxious particulate matter and gases. Partially oxidized compounds are also of great concern. For example, partial oxidation of ethanol produces harmful acetaldehyde and toxic CO. Therefore, pyrolysis of biofuels need be fully understood to describe their oxidation. Though the quality of combustion can be improved by changing the design of internal combustion engines, it is difficult to achieve 100% complete combustion. A better understanding of combustion characteristics of these fuels is required before their usage. Unless the deep mechanistic understanding of the decomposition of the proposed or emerging biofuels, it is almost impossible to predict the products.
In our laboratory, we use an inbuilt Single Pulse Shock Tube (SPST) to understand the thermal decomposition of these biofuels, important volatile organic compounds at elevated temperatures relevant to the combustion. SPST techniques is very unique in which a single thermal pulse is generated with a temperature gradient of a million degrees per second that survives for about a maximum of 800 microseconds. This thermal pulse heats the molecules to the desired temperature for such a short time. This means, the molecule under consideration is heated in the temperature zone of 1000 - 2500K and cooled to the room temperature instantaneously. The complete decomposition of the biofuel under consideration is investigated by analyzing the post decomposition products. State of the art diagnostic techniques such as GC-MS, GC-IR, GC with FID, TCD, ECD and NPD, FT-IR with very high resolution are used for this. Complete kinetic simulations are carried out to propose a probable mechanism of decomposition. Computational methods are extensively used to complement our experimental findings.
In addition to the above studies, atomic resonance absorption spectroscopic (ARAS) studies are planned to be carried out to understand the reactions of atoms such as hydrogen with biofuels in the high temperatures. Also, efforts are currently being made to use the laser induced fluorescence (LIF) technique to find the lifetimes of the transient species in the high temperature zone in SPST experiments.
The inbuilt Single Pulse Shock Tube (SPST) facility
A typical pressure trace recorded by an oscilloscope showing the arrival of primary, reflected shock waves, reaction time and expansion/cooling wave.(Rajakumar et al., J. Phys. Chem. A 2021, 125, 24, 5406-5422)
Sensitivity analysis of the proposed reaction scheme carried out at 1347 K for the formation of methane and ethylene.(Parandaman et al., RSC. Adv. 2015, 5, 86536-86550)
FTIR spectrum of the post-shock mixture of 2-MTHF decomposed at 1345 K. All the peaks are assigned to (A) 2-MTHF,(47) (B) methane,(44) (C) ethane,(44) (D) ethylene,(44) (E) 1,3-butadiene,(49) (F) acetylene,(44,48) (G) acetaldehyde,(44) (H) propylene,(44) (I) carbon monoxide,(48) (J) dihydromethylfuran,(50) and (K) cyclopropyl methyl ketone.(50) Inset plots shown are the expanded regions for CO, methane, and acetylene. [Rajakumar et al., J. Phys. Chem. A 2021, 125, 24, 5406-5422]
Thermal decomposition of 2-butanone - A case study: Comparison of experiment and simulation (Blue: Experiment & Green: Simulation)
[/su_tab] [su_tab title="COMPUTATIONAL CHEMISTRY"]Computational Chemistry
Computational Studies The usage of computational methods has become very important since the last two decades of the 20th century. In the event of lack of experimental data, computational methods offer a very reliable solutions. Even when experimental data are available, computational methods have become complementary tools for validation of the results. In other words, both experimental techniques and computational tools are complementary to each other. In our research laboratory, the computational methods are used to compute the kinetic parameters for the reactions of OH radicals, Cl atoms and NO3 radicals with varieties of compounds of interest in the Earth's atmosphere and combustion. Experimentally one can measure the overall rate coefficient for a reaction. But the information on the contribution of each site in the compound cannot be drawn so easily. Measurements with isotopic substituents should be carried out and they are very expensive. The site-specific contribution to a reaction can be easily estimated using computational methods. In addition, the contribution of type of reaction viz. addition or abstraction to the global rate can be estimated using computational methods. The transition state theory, variational transition state theory with necessary tunneling corrections are used for the calculation of rate coefficients. The branching ratios of varieties of channels in a reaction are estimated over the temperature using the computational studies. In the combustion process, understanding the mechanism is a challenging task especially in the high-temperature regime. The chemical kinetic simulations are an alternate way of understanding the decomposition mechanism of a compound. A proposed set of reactions with the known kinetic parameters can be used to compute the concentration of each and every species involved in the reaction. Kinetic situations can give us a guideline on the mechanism of a reaction. These studies are carried out in our laboratory to support the data obtained in the experimental facilities.
The movie shows the structure of a located transition state for the reaction between phenyl radical and ethyl acetate and how phenyl radical abstracts a hydrogen atom from ethyl acetate to form benzene as a stable product.
This movie shows the transition state obtained during the addition of Cl atom at a terminal position of 2,2,2-trifluoroethyl methacrylate. (Kumar et al., J. Phys. Chem. A. 2019, 123, 10868-10884)
Pressure dependent plots for the various reactions of R1OO• radicals at temperatures of 400, 1000 and 1500 K calculated using Rice-Ramsperger-Kassel-Marcus (RRKM) method which is incorporated in the MESMER 5.2 code (MESMER: Master Equation Solver for Multipotential Energy Well Reactions). [Kuzhanthaivelan et al., Combustion and Flame 2020, 219, 147-160]
To perform the computational calculations, at present we are using the AQUA supercluster, which is an indigenous facility provided by High Performance Computing Environment (HPCE), PG Senapathy Centre for Computing Resources at IIT Madras. The work by Prof. Rajakumar and his group was recently published in the HPCE highlight. HPCE Highlight of Prof. Rajakumar and his group [/su_tab] [su_tab title="MORE ABOUT OUR RESEARCH"]
Podcast: Hitchhiker's Guide to the Earth with Prof. B Rajakumar
Video Link: Podcast With Prof. B. Rajakumar
Video Link: Podcast With Prof. B. Rajakumar [/su_tab][su_tabs]